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HTTP 418: I'm a teapot

The server identifies as a teapot now and is on a tea break, brb

HTTP 418: I'm a teapot

The server identifies as a teapot now and is on a tea break, brb

Elimination Memes

Posts tagged with Elimination

Steric Hindrance: The Molecular Restraining Order

Chemistry Science
1 year ago 37.6K views 0 shares
Steric Hindrance: The Molecular Restraining Order
The drama in this chemical relationship is off the charts! That hydroxide ion (HO - ) is desperately trying to perform an elimination reaction with tert-butyl chloride, but the bulky methyl groups are like bouncers at an exclusive molecular club saying "NOPE!" This is classic steric hindrance - where those chunky methyl groups physically block the nucleophile from attacking. The molecule's panicked "AAAAAAAAHHHHH" is basically what your organic chemistry professor hears internally whenever students mix up SN1 and SN2 reactions. Chemistry's version of "it's not you, it's my bulky molecular structure."

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Back up Hugging Face models to a NAS before they vanish

Models do disappear from Hugging Face. How I keep a local copy I can verify: pinned hf download, SHA256 manifests, Ollama's blob store, and a ... Read article →

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